If you want to disconnect the negative side of the battery the switch will function properly and that is how some in the race industry do it when they need to kill the engines mid-race, but connecting the hot-side will act as a perfectly good theft deterrent and that is how just about every other keyed automobile works. Plus, if you run it on the ground side you have to use one big ass switch for those grounding cables vs. running itty bitty 10ga or whatever size your harness has for the fuel pump and the starter solenoid.
My M37 has a keyed ignition switch which controls power to the coil and the master battery disconnect is on the hot side of the battery. This disconnects any potential draws from the batteries when the truck is off. The marine industry and automotive industries use switches on the positive side of the battery to disconnect the ignition and fuel systems as well as to truly isolate the batteries, so I see no reason to try to reinvent the wheel.
Now, think about how you're going to connect that solar charger if you have a ground disconnect. You're going to have to wire it to both terminals on the battery to complete that circuit. Now, if that charger is connected and running while someone tries to steal it, they could, in theory have the proper closed circuit they need and you would see arcing on the ground side when that starter turns. It is unlikely, but depending on how you mount that charge panel, the negative side of the panel could ground itself through the mounts creating a frame mount to the battery terminal. This would have insanely high resistance, but it theoretically could work. If you disconnect the positive side there is no risk for this since everything is still grounded, but power is only flowing on the charger side and the rest of the power is cut to the truck. If the switch fails, you obviously have a problem, but if the switch fails on the ground side you still have a problem.
Not trying to be argumentative, but as an engineer you have to think of all potential problems and tailor the solution to your needs, which center around security against unauthorized ignition while still allowing the charging systems to function properly.