Yep, you could control the wire off the alt field relay(would still need a 24V coil relay).
I believe the excitation delay is there to save the alternator and regulator. While the starter is cranking, the battery voltage is very low. An alternator trying to come online at low RPM with a system voltage turned into a black hole while the starter cranks, will max out the field winding current. Very hard on the alt/reg, far easier on components to bring it online a few seconds later when engine/alt are up to idle RPM and batteries are now lightly loaded...