It is not so much of a problem with the 200 Amp dual voltage configuration. With this set up and using the 14 volt output to the rear battery you get the best of both worlds, A stable 12 volt circuit for your 12 volt goodies (reasonable, see my thread above) and both batteries are charged and equalized (this is important) for maximum output and life. This system allows for a bit of a mix-match of battery conditions
Where it becomes a headache is with the 60 Amp systems. (pay close attention cuz it's this simple) With the two batteries in series... two 12 volt batteries in series just like any 24 volt system... it would seem that one could just tap into the 12 volt battery and pull 12 volts. Yes, you can to a point. When you pull down that rear battery, you now might ?? have say 10.9 volts while running the 12 volt goodies. The front has say 11.9. So you had your fun playing the 12 volt radio listening to the ball game. Total system voltage both batteries 22.8. Games over and time to hit the road. That voltage should get you started and your on your way.
Here's where it get messy... (60 Amp system) The internal resistance and terminal voltage (10.9 & 11.9) of these two batteries above are different and will require (no two are alike, matched maybe from same batch?) So started truck, good. Voltmeter shows in the green GOOD more or less 28.5. Remember, it is a voltmeter. MEANS nothing to charging batteries in this condition, but at least the alternator is working.
Trying to charge this 60 Amp set-up of unequal batteries from a common 28.5 volt charging alternator due to the UNequal condition created above. The likelihood of the front battery having 15 to 16 volts across it and due the the lower internal resistance of the back battery... it will never see a complete charge. Note: front battery will boil out, smells like a fart... rear battery sits dead and never recovers and this thread starts all over again... can's start truck.
With the 60 Amp older system (many out there) are fine and will charge as designed with two EQUAL and MATCHED batteries FROM the SAME LOT and MAY work well with one type or another as in Los Vegas lucky.
Another OVERLOOKED headache is with the rear battery trying to charge and your now 12 /14 volt load in play, unequal voltages maybe flowing thru that equipment and keeping it simple... POOF!!! especially when on and trying to start. Undesired HIGH sneak currents with reverse voltage.
SO that the story from this FREE to you, how it works, no magic, no voodoo. Been there, seen it, done it.
There are ways around 60 Amp charging systems. Don't be fooled by the 60 Amp numbers. Running the truck and a small 24 volt military radio is fine and even better with the engine running.
Solid state 24 to 12 volt equalizer products are available that are acceptable, cost a bit of money and FULL understanding pro & con's to use.
Front and rear battery refers to NORMAL placement per TM of batteries.
Lead acid wet cells in series are a fine balancing act, to long life and few headaches, CAMO